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Changes in Chemical Structure and Hydrophobization of the Paulownia Wood with Fluorocarbon Resin | ||
| تحقیقات علوم چوب و کاغذ ایران | ||
| Article 43, Volume 35, Issue 2 - Serial Number 71, July 2020, Pages 178-194 PDF (898.35 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.22092/ijwpr.2020.341853.1601 | ||
| Authors | ||
| Aisona Talaei1; Mohammad Hadi Rezvani* 2; Hosseinali Rajabi Cham Heidari2 | ||
| 1Department, Faculty of Materials Engineering and New Technologies, shahid Rajaee Teacher Training University, Tehran, Iran | ||
| 2Wood Science and Technology Department, Faculty of Materials Engineering and New Technologies, Shahid Rajaee Teacher Training University, Tehran, Iran | ||
| Abstract | ||
| The widespread use of chemically/thermally modified wood in outdoor applications and in environments with high relative humidity and high temperature has doubled the importance of using hydrophobic monomers. To evaluate the effect of fluorocarbon modification as a binder on the physical properties and chemical structure of paulownia wood, thermal modification was performed at two temperature levels of 150 and 160°C and chemical modification with fluorocarbon at two levels of 15 and 25%. Chemical/thermal modification causes the fluorocarbon monomer and heat to be uniformly transferred into the wood and to reduce its hydrophilicity by causing chemical changes in the wood structure. Specimens were divided into control, thermal and thermal fluorocarbon treatment groups. The thermal fluorocarbon treatment caused modification of the hydroxyl groups and hydrophobicity in specimens. Infrared spectroscopy confirmed the presence of fluorocarbons and bonding with wood polymers. The fluorocarbon reaction resulted in chemical changes, weight gain and bulking of the specimens. The water uptake and volumetric swelling of the heat-treated fluorocarbon specimens were lower than the control and heat-treated ones. Improvement of water repellency efficiency and anti-swelling efficiency of thermal fluorocarbon specimens increased the dimensional stability compared to the thermal control and created a super hydrophobic and leak-resistant coating on the cell walls and inside the lumens. It was attributed to the greater penetration of fluorocarbons and the reduction of wood porosity. | ||
| Keywords | ||
| Chemical Modification; Fluorocarbon; Water Repellency Efficiency; Chemical Structure | ||
| References | ||
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